Search results for " Nanomaterials"
showing 10 items of 38 documents
Magnetic hybrid nanomaterials for the photodegradation of microcontaminats in aqueous environment
2018
Bio-based substances (BBS) isolated from urban biowaste have been employed to prepare hybrid magnetic nanomaterials with iron oxides. Such materials have been tested, in the presence of hydrogen peroxide, for the light induced photodegradation of four microcontaminants (MCs) in aqueous environment: Carbamazepine (C, an anticonvulsant and analgesic drug), Flumequine (F, an antibiotic), Ibuprofen (I, a non-steroidal anti-inflammatory drug), and Sulfamethoxazole (S, an antibiotic). Preliminary photodegradation experiments were carried out at lab-scale in a solar simulator, whereas optimized experiments were carried out in a pilot plant under natural solar radiation. The MCs complete abatement …
Atomically Precise Distorted Nanographenes: The Effect of Different Edge Functionalization on the Photophysical Properties down to the Femtosecond Sc…
2023
Nanographenes (NGs) have been attracting widespread interest since they combine peculiar properties of graphene with molecular features, such as bright visible photoluminescence. However, our understanding of the fundamental properties of NGs is still hampered by the high degree of heterogeneity usually characterizing most of these materials. In this context, NGs obtained by atomically precise synthesis routes represent optimal benchmarks to unambiguously relate their properties to well-defined structures. Here we investigate in deep detail the optical response of three curved hexa-peri-hexabenzocoronene (HBC) derivatives obtained by atomically precise synthesis routes. They are constituted…
Nanodiamond Theranostic for Light-Controlled Intracellular Heating and Nanoscale Temperature Sensing
2021
Temperature is an essential parameter in all biological systems, but information about the actual temperature in living cells is limited. Especially, in photothermal therapy, local intracellular temperature changes induce cell death but the local temperature gradients are not known. Highly sensitive nanothermometers would be required to measure and report local temperature changes independent of the intracellular environment, including pH or ions. Fluorescent nanodiamonds (ND) enable temperature sensing at the nanoscale independent of external conditions. Herein, we prepare ND nanothermometers coated with a nanogel shell and the photothermal agent indocyanine green serves as a heat generato…
Nanostructured Based Electrochemical Sensors.
2019
In this work, we present some results concerning the electrochemical behavior of nanostructured-based electrochemical sensors. In particular, the attention has been focused on Pd and Cu nanowires for detection of hydrogen peroxide and NiO thin film or Ni@NiO core–shell nanowires for detection of mercury ions. Ordered array of Pd and Cu nanowires was obtained through displacement deposition reaction in a commercial polycarbonate membrane acting as a template. The method leads to stable nanostructured electrodes of Pd and Cu with high surface area. For the detection of mercury ions, we have fabricated a Ni/NiO electrochemical sensor, obtained by mild thermal oxidation of Ni-foil. Some results…
Physical–chemical properties of biogenic selenium nanostructures produced by stenotrophomonas maltophilia SeITE02 and ochrobactrum sp. MPV1
2018
Stenotrophomonas maltophilia SeITE02 and Ochrobactrum sp. MPV1 were isolated from the rhizosphere soil of the selenium-hyperaccumulator legume Astragalus bisulcatus and waste material from a dumping site for roasted pyrites, respectively. Here, these bacterial strains were studied as cell factories to generate selenium-nanostructures (SeNS) under metabolically controlled growth conditions. Thus, a defined medium (DM) containing either glucose or pyruvate as carbon and energy source along with selenite (SeO23−) was tested to evaluate bacterial growth, oxyanion bioconversion and changes occurring in SeNS features with respect to those generated by these strains grown on rich media. Transmissi…
Photo-thermal effects in gold nanorods/DNA complexes
2015
An ingenious combination of plasmonic nanomaterials and one of the most relevant biological systems, deoxyribonucleic acid (DNA) is achieved by bioconjugating gold nanorods (GNRs) with DNA via electrostatic interaction between positively charged GNRs and negatively charged short DNA. The obtained system is investigated as a function of DNA concentration by means of gel electrophoresis, zeta-potential, DNA melting and morphological analysis. It turns out that the obtained bioconjugated systems present both effective electric charge and aggregate size that are particularly amenable for gene therapy and nanomedicine applications. Finally, the effect of the localized (photo-thermal heating) and…
Nanotechnologies for Active and Intelligent Food Packaging: Opportunities and Risks
2017
This chapter focuses on providing a comprehensive review on the current development of nanotechnology in the field of active and intelligent packaging for food. Systems devoted to intelligent food packaging require easy-to-read, cheap, robust, and safe systems that are able to provide on time information. Food and Drug Administration (FDA) considers that evaluations of safety, effectiveness, public health impact, or regulatory status of nanotechnology products should consider any unique properties and behaviors that the application of nanotechnology may impart. The lack of regulatory support providing standardized risk assessments of engineered nanomaterials (ENM) through integration of haz…
Nanotechnology for Conservation: The Case of Archaeological Sites
2006
L'articolo espone le principali problematiche conservative dei siti archeologici e analizza la possibilità di applicazione dei nuovi nanomateriali, derivanti dalle nanotecnologie come soluzioni innovative per affrontare problematiche irrisolte con i prodotti tradizionali. The article presents the main conservation problems of archaeological sites and analyzes the possibility of new nanomaterials application, deriving from nanotechnologies as innovative solutions to address unresolved problems with traditional products.
Carbon based nanomaterials for tissue engineering of bone: Building new bone on small black scaffolds: A review.
2019
Graphical abstract
Analysis of emerging contaminants and nanomaterials in plant materials following uptake from soils
2017
The reuse of treated wastewater or wastewater-impacted river water is growing, particularly in arid areas, due to the climate change. As well, the disposal of sludges, biosolids or biochar as soil amendments to improve agricultural output is widely implemented in the EU. These practices can be a source of emerging contaminants and engineering nanomaterials (ENMs) to the environment and condition their incorporation to food chain that could affect human beings. This review covers current analytical techniques, instruments and methodologies used to determine emerging contaminants and ENMs from irrigation water and/or soil amendments in plants. Trends regarding sample treatment, separation and…